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Kalina Cycle

Heat Engine

The Kalina cycle is a thermodynamic process for converting thermal energy into usable mechanical power, developed by Alexander Kalina, that uses a working fluid made of two components with different boiling points, commonly water and ammonia, instead of a single pure fluid. Because the mixture boils and condenses over a range of temperatures rather than at one fixed point, the cycle extracts more heat from its source and rejects less to its sink than a comparable Rankine cycle, reaching efficiency close to a combined cycle plant with less mechanical complexity. It is used to recover waste heat from steel mills, oil refineries and cement plants, and to generate power from geothermal and solar heat sources; installed examples include a 3.6 megawatt unit at the Kashima Steel Works in Japan running since 1999 and a 3.4 megawatt geothermal plant at Unterhaching in Germany commissioned in 2009.

Facts
Technology Type
Binary fluid power cycle 2
Invented Year
1985 2
1985 is the grant date of Alexander Kalina's US patent 4548043A, filed 1984, the founding patent for the cycle.
Classification
Maturity
TRL 9: Actual System Proven in Operational Environment 1
Sources
1. Kalina cycle - Wikipedia
Technology maturity, Wikipedia introduction extract fetched 2026-09-25
Quote, Technology maturity, Wikipedia introduction extract fetched 2026-09-25
Water and ammonia is the most widely used combination, but other combinations are feasible.
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2. Google Patents: US4548043A (Kalina, Method of Generating Energy)
Google Patents
  • Description section, background paragraph
    Applicants prior U.S. Pat. No. 4,346,561 filed Apr. 24, 1980 relates to a system for generating energy which utilizes a binary or multicomponent working fluid.
  • Patent metadata block, Inventor and Publication date fields
    Inventor Alexander I. Kalina Publication date 1985-10-22
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