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Chemical Looping Combustion

Emissions Control

Chemical looping combustion, or CLC, is a combustion technology built around a dual fluidized-bed system in which a metal oxide, rather than atmospheric air, supplies the oxygen needed for combustion. In the fuel reactor the metal oxide releases its oxygen to burn the fuel and is itself chemically reduced; the reduced metal then moves to a separate air reactor, where it is re-oxidized before returning to the fuel reactor to begin the cycle again. Because the fuel is never mixed directly with air, chemical looping combustion avoids forming nitrogen oxide pollutants, and the process yields two separate exhaust streams, one of mostly atmospheric gases with very little carbon dioxide, the other of mostly carbon dioxide and water vapor; simply condensing the water vapor out of that second stream yields nearly pure carbon dioxide, allowing efficient carbon capture without the energy penalty that conventional capture methods carry.

Facts
Technology Type
A combustion technology that circulates a metal oxide oxygen carrier between two reactors to burn fuel without direct contact with air, simplifying carbon dioxide capture 1
Invented Year
2003 1
First proposed conceptually by Lewis, Gilliland and Sweeney in 1951; first demonstrated operation with gaseous fuels was 2003.
Classification
Maturity
TRL 7: System Prototype Demonstration in Operational Environment 1
Sources
1. Wikipedia: Chemical looping combustion
Wikipedia
  • Development history section
    First operation of chemical-looping combustion with gaseous fuels was demonstrated in 2003.
  • In Group: Carbon Capture, Lead
    Chemical looping combustion (CLC) is a technological process typically employing a dual fluidized bed system.
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